Exceptionally Long-Lived Luminescence from [Cu(I)(isocyanide)2(phen)]+ Complexes in Nanoporous Crystals Enables Remarkable Oxygen Gas Sensing
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We report crystalline mixed-ligand copper complexes with phenanthroline and isocyanides with almost millesecond emission lifetimes that are efficient dioxygen sensors. The oxygen sensitivity of the prototype ([Cu(CN-xylyl)2(dmp)]tfpb, dmp = 2,9-dimethyl-1,10-phenanthroline; CN-xylyl = 2,6-dimethylphenylisocyanide; tfpb = tetrakis(bis-3,5-trifluoromethylphenylborate) is 38 times better than that of [Ru(phen)3]tfpb2 (phen = 1,10-phenanthroline).
创建时间：
2016-02-20
