Zwitterionic, Ring-Borylated Vanadium(III) Complexes from [Cp<sub>2</sub>VCO] and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The reaction of the vanadium(II) carbonyl [Cp2V(CO)] and B(C6F5)3 resulted in formation of zwitterionic, ring-borylated vanadium(III) complexes [(Cp)(C5H4B(C6F5)3)V] (3) and [(Cp)(C5H4B(C6F5)3)V(CO)2] (4) and of the salt [Cp2V(CO)2][HB(C6F5)3] (5). All were characterized by crystallography. Formation of a hydride vanadium(IV) [(Cp)(C5H4B(C6F5)3)VH(CO)] obtained by the electrophilic addition of the borane at the Cp-ring followed by redox and disproportionation reaction is suggested to account for these results.
创建时间：
2016-05-07
