NewSOC, supplementary information to WT2.5.4 "Cells with honeycomb structured oxygen electrodes": electrochemical and post-mortem data sets.

These are data set, related to participation of the IEN in project NewSOC. It includes results of the SEM-EDS analysis of the cells with hexagonal current collecting net and electrochemical performance data, both EIS and C-V characteristics. Results are grouped in zip archives, named according to cell design, “infill-net”.

Compositions:

LNF – LaNi0.6Fe0.4O3 (net)

LSC – La0.6Sr0.4CoO3-d (infill)

LSF – La0.5Sr0.5FeO3-d (infill)

LSCCF – La0.6Sr0.4Co0.15Cu0.05Fe0.8O3-d (net)

PCM – Pr0.5Ca0.5MnO3 (net)

BSCFM – Ba0.5Sr0.5Co0.725Fe0.2Mo0.075O3-d (infill)

Data presentation.

C-V characteristics:

This is text files, generated by Zahner galvanostat, with self-decriptional titles.

“05iv_650c_100h2+100h2o_500air.txt” –  measurement at 650°C, 100 mL/min H2 and 100 mL/min H2O on fuel side, 500 mL/min of air on air side.

EIS data:

EIS results were extracted from proprietary binary files, generated by Zahner galvanostat, and raw data is generally meaningless except the owners of such hardware. So, extracted EIS can be found in Excel files, used in analysis, in sheet “Experimental”. Other sheets in xlsx include some metadata (“info”), results of the equivalent circuit fit (“fit”) and some plots. Fit results might not be relevant.  

SEM

Post-mortem results presented as SEM images (tif or jpg files) and pdf files with results of the EDS analysis.

LSC-LNF

(air flow 1 L/min, current density 0.25 A/cm2)

test_1_07:  

03_eis20200917142808.xlsx – EIS, SOFC, 700°C, Flows L/min: F:0.2 H2;

05_eis20200917123105.xlsx – EIS, SOFC, 700°C, flows L/min: F:0.1 H2+ 0.1 H2O;

08_eis20200917123857.xlsx – EIS, SOFC, 700°C, flows L/min: F:0.1 H2+ 0.1 H2O;

10_eis20200917131537.xlsx – EIS, SOEC, 700°C, flows L/min: F:0.1 H2+ 0.1 H2O;

test_1_08:

03_eis20200917125707.xlsx – EIS, SOFC, 700°C, Flows L/min: F:0.2 H2;

09_eis20200917130019.xlsx – EIS, SOEC, 700°C, flows L/min: F:0.09 H2+ 0.21 H2O;

10_eis20200917130600.xlsx – EIS, SOFC, 700°C, flows L/min: F:0.06 H2+ 0.14 H2O;

12_eis20200917130737.xlsx – EIS, SOEC, 700°C, flows L/min: F:0.12 H2+ 0.28 H2O;

test_3_14:

01_eis20210517102042.xlsx– EIS, SOFC, 700°C, Flows L/min: F:0.1 H2+0.1 N2; 05_eis20210517102625.xlsx– EIS, SOFC, 700°C, flows L/min: F:0.1 H2+ 0.1 H2O;

07_eis20210517102305.xlsx– EIS, SOEC, 700°C, flows L/min: F:0.06 H2+ 0.14 H2O;

SEM

(post-mortem after test_1_07)

ogniwo_310_2020  ****.jpg - surface

BSCMF-PCM

(SOFC, air flow 0.5 L/min)

test_2_14

01eis_700c_cc4a_100h2+100n2_500air_eqc20220110112836.xlsx –700°C, 0.25 A/cm2 Flows L/min: F:0.1 H2+0.1 N2

02eis_700c_cc4a_100h2+100h2o_500ai_eqc20220110112724.xlsx –700°C, 0.25 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

04eis_650c_cc3a_100h2+100h2o_500ai_eqc20220110112503.xlsx–650°C, 0.1875 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

06eis_650c_cc3a_100h2+100n2_500air_eqc20220110112332.xlsx –650°C, 0.1875 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

07eis_625c_cc3a_100h2+100n2_500air_eqc20220110112214.xlsx –625°C, 0.125 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

08eis_625c_cc3a_100h2+100h2o_500ai_eqc20220110111834.xlsx–625°C, 0.125 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

test_1_67

01_eqc20220831134628.xlsx–700°C, 0.125 A/cm2 Flows L/min: F:0.1 H2+0.1 N2

02_eqc20220831134724.xlsx - 700°C, 0.25 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

04_eqc20220831135442.xlsx–650°C, 0.0625 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

06_eqc20220831135622.xlsx - 650°C, 0.0625 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

08_eqc20220831135801.xlsx - 625°C, 0.0625 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

09_eqc20220831135933.xlsx –650°C, 0.0625 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

SEM

(post-mortem of the test_2_14)

493-2021-1.pdf, 493-2021-1i.pdf, 493-2021-2.pdf, 493-2021-2-2.pdf, 493-2021-2-3.pdf –cross-sections with EDS

493_2021_*_**.tif  - cross-sections

BSCMF-LSCCF

(SOFC, air flow 0.5 L/min)

                               test_2_08

01_eis20211104144342.xlsx - 700°C, 0.25 A/cm2 Flows L/min: F:0.1 H2+0.1 N2

03eis_700c__eis20211108102241.xlsx - 700°C, 0.25 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

04eis_700c__eis20211108102401.xlsx - 700°C, 0.25 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

08eis__eis20211110094642.xlsx - 650°C, 0.1875  A/cm2 Flows L/min: F:0.1 H2+0.1 N2

10eis__eis20211110094945.xlsx - 650°C, 0.1875 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

11eis__eis20211110101358.xlsx - 625°C, 0.125 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

13eis__eis20211110100837.xlsx- 625°C, 0.125 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

                               test_2_26

04_eqc20220817114103.xlsx - 700°C, 0.25 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

06_eqc20220817121529.xlsx - 700°C, 0.25 A/cm2 Flows L/min: F:0.1 H2+0.1 N2

07_eqc20220802084119.xlsx - 650°C, 0.1875  A/cm2 Flows L/min: F:0.1 H2+0.1

08_eqc20220802084616.xlsx - 650°C, 0.1875 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

10_eqc20220802150705.xlsx - 625°C, 0.125 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

11_eqc20220802150108.xlsx - 625°C, 0.125 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

SEM

(post-mortem of the test_2_26)

661_BSCMF_LSCCF_p.pdf  – cross-section with EDS

661_BSCMF_LSCCF_PM.pdf - surface with EDS

661_BSCMF_LSCCF_p_01.tif, 661_BSCMF_LSCCF_p_02.tif, 661_BSCMF_LSCCF_p_03.tif, 661_BSCMF_LSCCF_p_04.tif  -  cross-section, infill zone

661_BSCMF_LSCCF_p_05.tif, 661_BSCMF_LSCCF_p_06.tif - cross-section, net zone zone

661_BSCMF_LSCCF_PM_**.tif  - surface

LSF-LSCCF

(SOFC, air flow 0.5 L/min)

test_1_65

01_eqc20220816105347.xlsx - 700°C, 0. 1875 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

02_eqc20220816105941.xlsx - 700°C, 0. 1875 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

04_eqc20220816112311.xlsx - 650°C, 0. 125 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

06_eqc20220816111640.xlsx - 650°C, 0.125 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

07_eqc20220816142436.xlsx- 625°C, 0.0625 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

08_eqc20220816142842.xlsx-625°C, 0.625 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

SEM

(post-mortem)

663_LSF_LSCCF_p.pdf – cross-section with EDS

663_LSF_LSCCF_PM.pdf - surface with EDS

663_LSF_LSCCF_P_GR_**.tif – cross-section of the cell

663_LSF_LSCCF_P_LSCCF_**.tif – surface of the LSCCF grid

663_LSF_LSCCF_PM_**.tif - surface of the LSF infill

LSF-PCM

(SOFC, air flow 0.5 L/min)

tests_1_66

01_eqc20220831133210.xlsx - 700°C, 0. 125 A/cm2 Flows L/min: F:0.1 H2+0.1 N2

02_eqc20220831133409.xlsx - 700°C, 0. 125 A/cm2 Flows L/min: F:0.1 H2+0.1 N2

03_eqc20220831133928.xlsx - 700°C, 0. 125 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

05_eqc20220831134048.xlsx - 650°C, 0.0625  A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

06_eqc20220831134142.xlsx - 650°C, 0.0625 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

08_eqc20220831134237.xlsx - 625°C, 0.0625 A/cm2 Flows L/min: F:0.1 H2+0.1 H2O;

10_eqc20220831134412.xlsx - 625°C, 0.0625 A/cm2 Flows L/min: F:0.1 H2+0.1 N2;

SEM

(post-mortem)

658_LSF_PCM_p.pdf – cross-section with EDS

658_LSF_PCM_PM.pdf - surface with EDS

658_LSF_PCM_P_LSF_**.tif  – cross-section, infill zone

658_LSF_PCM_P_pcm_**.tif - cross-section, net zone

658_LSF_PCM_PM_**.tif - surface

description.pdf - pdf version of this information.