[Rh{NC<sub>5</sub>H<sub>3</sub>-2,6-(CH<sub>2</sub>P<sup>t</sup>Bu<sub>2</sub>)<sub>2</sub>}(PCy<sub>3</sub>)][BAr<sup>F</sup><sub>4</sub>]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
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An expedient new route to the cationic [(PNPtBu)Rh(L)]+ metal fragments (PNPtBu = κ3-NC5H3-2,6-(CH2P tBu2)2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNPtBu)Rh(H2)][BArF4]. [(PNPR)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center.
创建时间：
2011-08-22
