Catalytic Carbon−Hydrogen Bond Functionalization in an Ionic Liquid Medium
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https://figshare.com/articles/dataset/Catalytic_Carbon_Hydrogen_Bond_Functionalization_in_an_Ionic_Liquid_Medium/2968567
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资源简介:
The functionalization of unreactive C−H bonds of several hydrocarbons has been achieved at room temperature by the formal insertion of carbene/CHCO2Et units (from ethyl diazoacetate) into such bonds, using copper-based catalysts in a biphasic reaction medium (ionic liquid-hydrocarbon). Catalyst and product separation has been carried out easily, and the recycle of the catalyst for five cycles has been achieved without any loss of catalytic activity.
创建时间:
2007-12-17



