Asymmetric Total Synthesis of Rumphellclovane E
收藏Figshare2020-12-24 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Asymmetric_Total_Synthesis_of_Rumphellclovane_E/13488316
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资源简介：
The first asymmetric total synthesis of rumphellclovane E, a clovane-type sesquiterpenoid, has been accomplished in eight steps from commercially available (R)-carvone. Key elements of the synthesis include Rh-catalyzed cyclopropanation, iron-catalyzed intramolecular reductive aldol reaction, and SmI2-mediated chemo- and diastereoselective reduction of the cyclopentanone.
创建时间：
2020-12-24
