Rational Synthesis of Mixed-Metal Microporous Metal–Organic Frameworks with Controlled Composition Using Mechanochemistry
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https://figshare.com/articles/dataset/Rational_Synthesis_of_Mixed-Metal_Microporous_Metal_Organic_Frameworks_with_Controlled_Composition_Using_Mechanochemistry/9159911
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资源简介：
Mechanochemistry
enables targeted, rapid synthesis of bimetallic
metal–organic frameworks (MOFs) with a controlled 1:1 stoichiometric
composition of metal nodes. In particular, ball milling enabled the
use of specifically synthesized solid coordination complexes of Zn(II),
Mg(II), Ni(II), and Co(II) for the assembly of a range of microporous
mixed-metal MOF-74 materials composed of pairs of d-block or main group metals in a predetermined 1:1 stoichiometric
ratio, including ZnMg-, ZnCo-, ZnCu-, MgZn-, MgCo-, NiZn-, NiMg-,
NiCo-, CoZn-, CoMg-, CoCu-, and MgCa-MOF-74. By using specifically
prepared precursors in the synthesis of diverse mixed-metal MOF-74
targets, this rational synthesis represents the first entry of mechanochemistry
into the target-oriented synthesis of mixed-metal MOFs.
创建时间：
2019-07-11
