Synthesis, Structure, and Properties of a Stable 1,2-Dibromodialumane(4) Bearing a Bulky Aryl Substituent
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The stable 1,2-dibromodialumane(4) Bbp(Br)Al–Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr2·OEt2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.
创建时间：
2016-02-20
