Materials Data on Ag3Sb4F24 by Materials Project

Ag3(SbF6)4 crystallizes in the cubic I-43d space group. The structure is three-dimensional. Ag+1.33+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are four shorter (2.34 Å) and four longer (2.84 Å) Ag–F bond lengths. Sb5+ is bonded in an octahedral geometry to six F1- atoms. There is three shorter (1.90 Å) and three longer (1.94 Å) Sb–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to one Ag+1.33+ and one Sb5+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Ag+1.33+ and one Sb5+ atom.