Probing Dynamic Library of Metal-Oxo Building Blocks with γ‑Cyclodextrin
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https://figshare.com/articles/dataset/Probing_Dynamic_Library_of_Metal-Oxo_Building_Blocks_with_Cyclodextrin/7045046
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资源简介：
Formation
of one of the most representative polyoxometalate (POM)
archetypes, namely the Lindqvist anion M6O192– with M = MoVI or WVI,
was considered as elusive in aqueous solution. Herein, we report on
the host–guest stabilization of the M6O192– species with M = Mo or W from aqueous solution
using γ-cyclodextrin as trapping agent. The adduct {M6O19@γ-CD}2– reveals remarkable
hydrolytic stability that offers new opportunities for exploring potentialities
of molybdates or tungstates in the field of biology and medicine,
when combined to CDs as efficient drug carrier/delivery agents.
创建时间：
2018-09-04
