Total Synthesis and Stereochemical Assignment of (±)-Sorbiterrin A
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https://figshare.com/articles/dataset/Total_Synthesis_and_Stereochemical_Assignment_of_Sorbiterrin_A/2029593
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A concise, biomimetic approach to sorbiterrin A has been developed employing consecutive Michael additions of a 4-hydroxypyrone to a sorbicillinol derivative and silver nanoparticle-mediated bridged aldol/dehydration to construct the [3.3.1] ring system. The relative stereochemistry of sorbiterrin A was unambiguously confirmed by X-ray crystallographic analysis.
创建时间：
2015-12-17
