Isolation of Ruthenium–Indolizine Complexes: Insight into the Metal-Induced Cycloisomerization of Propargylic Pyridines
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https://figshare.com/articles/dataset/Isolation_of_Ruthenium_Indolizine_Complexes_Insight_into_the_Metal_Induced_Cycloisomerization_of_Propargylic_Pyridines/2398255
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A class of ruthenium–indolizine complexes was isolated and structurally characterized, and they represent the first examples of metalated indolizine species. Both experimental and theoretical investigations on the formation of these complexes support a 5-endo-dig cyclization mechanism and discount a vinylidene–5-exo-dig cyclization pathway.
创建时间：
2016-02-19
