Solution and Solid-State Structures of Lithiated Phenyloxazolines
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Solution_and_Solid_State_Structures_of_Lithiated_Phenyloxazolines/3052495
下载链接
链接失效反馈官方服务：
资源简介：
The structures of three ortho-lithiated phenyloxazolines, the parent (1), the para-tert-butyl analogue
(2), and the para-chloro analogue (3), were studied in solution. All three compounds are mixtures of
monomers and dimers in THF/ether mixed solvents, with 2 the most aggregated and 3 the least. They are
converted to monomers with HMPA and PMDTA. In the PMDTA complexes, the lithium appears to
still be chelated to the oxazoline ring. Single-crystal X-ray structures were obtained for 1 and 2. Both are
centrosymmetric dimers of B-type (each lithium coordinated to one oxazoline ring).
创建时间：
2016-02-29
