Catalytic B–N Dehydrogenation Using Frustrated Lewis Pairs: Evidence for a Chain-Growth Coupling Mechanism
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Catalytic_B_N_Dehydrogenation_Using_Frustrated_Lewis_Pairs_Evidence_for_a_Chain_Growth_Coupling_Mechanism/3084301
下载链接
链接失效反馈官方服务：
资源简介：
The catalytic dehydrogenation
of ammonia- and amine-boranes by
a dimethylxanthene-derived frustrated Lewis pair is described. Turnover
is facilitated on a thermodynamic basis by the ready release of H2 from the weakly basic PPh2-containing system. In situ NMR studies and the isolation of intermediates from
stoichiometric reactions support a mechanism initiated by B–H
activation, followed by end-growth BN coupling involving the terminal
NH bond of the bound BN fragment and a BH bond of the incoming borane
monomer.
创建时间：
2016-03-25
