Copper-Catalyzed Trifluoromethylselenolation of Aryl and Alkyl Halides: The Silver Effect in Transmetalation
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Copper_Catalyzed_Trifluoromethylselenolation_of_Aryl_and_Alkyl_Halides_The_Silver_Effect_in_Transmetalation/2331607
下载链接
链接失效反馈官方服务：
资源简介：
A catalytic
trifluoromethylselenolation of aryl and alkyl halides
by a Cu(I) catalyst has been developed. A key intermediate, [(phen)Cu(SeCF3)]2 (5) was successfully isolated
and characterized by X-ray diffraction. The important role of silver
in the transmetalation process during the catalytic cycle was elucidated.
A wide range of trifluoromethylselanes have been prepared from readily
available starting materials from a method that tolerates various
important functional groups.
创建时间：
2016-02-18
