Catalytic Annulation of Diethyl Methylenecyclopropane-1,1-dicarboxylate with 1,1-Dicyanoalkenes
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The catalytic annulation of methylenecyclopropane 1 with 1,1-dicyanoalkenes 2 using a Mg–Sn catalytic system was developed. Selective formation of cyclopentylidenemalonates 3 and spiro[2,3]hexane-1,1-dicarboxylates 4 was accomplished via the choice of a proper solvent and an effective catalytic system.
创建时间:
2017-05-01



