Mononitrosyl Iron Complexes Supported by Sterically Hindered Carboxylate Ligands
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https://figshare.com/articles/dataset/Mononitrosyl_Iron_Complexes_Supported_by_Sterically_Hindered_Carboxylate_Ligands/3056416
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资源简介：
Complexes that feature a single NO bound to Fe, as postulated
in various carboxylate-rich metalloproteins, were prepared by mixing
FeII salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate
(Mes2ArCO2-). Among the compounds isolated are the potentially
useful heterobimetallic synthon Tl(μ-Mes2ArCO2)3Fe(NO) and a
novel cubane Fe4(Mes2ArCO2)4(NO)4(μ3-OH)4 that forms in the
presence of added H2O and features syn-[FeNO]2 units.
创建时间：
2006-10-02
