CO2 Capture by a Rhenium(I) Complex with the Aid of Triethanolamine
收藏Figshare2016-06-06 更新2026-04-29 收录
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https://figshare.com/articles/dataset/CO_sub_2_sub_Capture_by_a_Rhenium_I_Complex_with_the_Aid_of_Triethanolamine/2026587
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A rhenium(I) tricarbonyl diimine complex with a N,N-dimethylformamide ligand captures one CO2 molecule in the presence of triethanolamine (TEOA), giving fac-[ReI(bpy)(CO)3{R2N-CH2CH2O-COO}] (bpy = 2,2′-bipyridine, R = CH2CH2OH). This could be a predominant complex in various photocatalytic CO2 reduction reactions using [ReI(N^N)(CO)3X]n+ (N^N = diimine ligand; X = monodentate ligand; n = 0, 1) type complexes in the presence of TEOA.
创建时间:
2016-06-06



