Room-Temperature Characterization of a Mixed-Valent μ‑Hydroxodicopper(II,III) Complex
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https://figshare.com/articles/dataset/Room-Temperature_Characterization_of_a_Mixed-Valent_Hydroxodicopper_II_III_Complex/3573969
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资源简介:
Bis(μ-hydroxo)dicopper(II,II)
bearing a naphthyridine-based ligand has been synthesized and characterized
in the solid state and solution. Cyclic voltammetry at room temperature
displays a reversible redox system that corresponds to the monoelectronic
oxidation of the complex. Spectroscopic and time-resolved spectroelectrochemical
data coupled to theoretical results support the formation of a charge-localized
mixed-valent CuII,III2 species.
创建时间:
2016-08-31



