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Selective Preparation of Diamondoid Phosphonates

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Selective_Preparation_of_Diamondoid_Phosphonates/2285443
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We present an effective sequence for the preparation of phosphonic acid derivatives of the diamondoids diamantane, triamantane, [121]­tetramantane, and [1­(2,3)­4]­pentamantane. The reactions of the corresponding diamondoid hydroxy derivatives with PCl3 in sulfuric or trifluoroacetic acid give mono- as well as didichlorophosphorylated diamondoids in high preparative yields.
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2014-06-06
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