Selective Preparation of Diamondoid Phosphonates
收藏NIAID Data Ecosystem2026-03-08 收录
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We present an effective sequence for the preparation of phosphonic acid derivatives of the diamondoids diamantane, triamantane, [121]tetramantane, and [1(2,3)4]pentamantane. The reactions of the corresponding diamondoid hydroxy derivatives with PCl3 in sulfuric or trifluoroacetic acid give mono- as well as didichlorophosphorylated diamondoids in high preparative yields.
创建时间：
2014-06-06
