Pd(0)/InI-Mediated Allylic Additions to 4-Acetoxy-2-azetidinone: New Route to Highly Functionalized Carbocyclic Scaffolds
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
Acylnitroso-derived hetero-Diels−Alder cycloadducts are susceptible to C−O bond cleavage with Pd(0) and InI to form allylic indium(III) species. The in situ prepared allylindium compounds readily react at room temperature with Eschenmoser’s salt. Allylation of 4-acetoxy-2-azetidinone provides derivatized cyclopentenes in high regio- and diastereoselectivity.
创建时间：
2016-02-26
