Large (H<sub>2</sub>O)<sub>56</sub>(OH)<sub>6</sub> and (H<sub>2</sub>O)<sub>20</sub> Clusters inside a Nanometer-Sized M<sub>6</sub>L<sub>8</sub> Cage Constructed by Five-Coordinated Copper(II) and Flexible Carboxamide-Containing Tripodal Ligand
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N′,N″,N′′′-Tris(pyrid-4-ylmethyl)-1,3,5-benzenetricarboxamide (TPMBA-4) reacts with Cu(BF4)2·6H2O to form a zero-dimensional cagelike complex [CuII6(OH)6(TPMBA-4)8](BF4)3(OH)3·85H2O (1). Interestingly, X-ray crystallographic analysis revealed that large (H2O)76(OH)6 clusters with outer-shell (H2O)56(OH)6 and inner-hosted (H2O)20 ones are encapsulated in the cavity of 1. It presents a new mode of association of water molecules for research on water or ice.
创建时间：
2016-02-27
