Gold-Catalyzed [1,5]-Hydride Shift onto Unactivated Alkynes To Trigger an Intermolecular Diels–Alder Reaction
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https://figshare.com/articles/dataset/Gold_Catalyzed_1_5_Hydride_Shift_onto_Unactivated_Alkynes_To_Trigger_an_Intermolecular_Diels_Alder_Reaction/2273362
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资源简介：
A [1,5]-hydride
shift of sp3 C–H onto an unactivated
carbon–carbon triple bond catalyzed by a gold(I) complex enabled N-propargylisoindolines to be latent dienes and therefore
triggered an intermolecular Diels–Alder reaction with dienophiles.
This protocol provides an atom-economical and straightforward approach
to access a wide range of polycyclic skeletons in high yields and
with excellent diastereoselectivities from easily accessible molecules.
创建时间：
2016-02-17
