C–H Bond Activation of the Methyl Group of the Supporting Ligand in an Osmium(III) Complex upon Reaction with H2O2: Formation of an Organometallic Osmium(IV) Complex
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https://figshare.com/articles/dataset/C_H_Bond_Activation_of_the_Methyl_Group_of_the_Supporting_Ligand_in_an_Osmium_III_Complex_upon_Reaction_with_H_sub_2_sub_O_sub_2_sub_Formation_of_an_Organometallic_Osmium_IV_Complex/2450719
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Oxidation of the hydroxoosmium(III) complex resulted in C–H bond activation of the methyl group of the supporting ligand (N,N′-dimethyl-2,11-diaza[3.3](2,6)pyridinophane). The product was an osmium(IV) complex exhibiting a seven-coordinate structure with an additional Os–CH2 bond.
创建时间:
2016-02-20



