A High pressure investigation of the Manganese Carbonyls Mn(CO)5(CH3) and Mn(...

B2FIND2026-04-25 收录

高压化学

有机金属催化

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https://b2find.eudat.eu/dataset/2ea18dcd-4ce9-542c-845b-ae6561a1757b 数据链接链接失效反馈

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Organometallic compounds play an important role in catalysis, and compounds with metal carbonyl groups have been studied at elevated pressure by vibrational spectroscopy, but...

Tantallacarborane Mediated Consecutive C–C and C–N Coupling Reactions of Alkyl Isonitriles: A Facile Route to N‑Heterocycles

有机金属催化

杂环化合物构建

Reactions of tantallacarborane methyl complexes ([η1:η5-(Me2NCH2CH2)C2B9H10]TaMe3 (1) and [η1:η5-(MeOCH2CH2)C2B9H10]TaMe3 (8)) with alkyl isonitriles have been studied. Complex 1 reacted with 1 eq

Figshare2016-02-12 更新70

Hydrosilylation of Terminal Alkynes Catalyzed by a ONO-Pincer Iridium(III) Hydride Compound: Mechanistic Insights into the Hydrosilylation and Dehydrogenative Silylation Catalysis

有机金属催化

氢硅化反应

The catalytic activity in the hydrosilylation of terminal alkynes by the unsaturated hydrido iridium(III) compound [IrH(κ3-hqca)(coe)] (1), which contains the rigid asymmetrical dianionic ONO pince

NIAID Data Ecosystem60

Selective Boryl Silyl Ether Formation in the Photoreaction of Bisboryloxide/Boroxine with Hydrosilane Catalyzed by a Transition-Metal Carbonyl Complex

有机金属催化

硼烷化合物合成

Selective B–O–Si bond formation was achieved in the reaction of bisboryloxide O(Bpin)2 (pin = (OCMe2)2)/boroxine (MeBO)3 system with tertiary silane R3SiH in the presence of stoichiometric water and

NIAID Data Ecosystem60

Selective Cleavage of the C−C Bonds of Aminoethyl Groups, via a Multistep Pathway, by a Pincer Iridium Complex

有机金属催化

C-C键选择性裂解

A pincer-ligated iridium complex is found to react with N-ethylamines, HN(Et)R (R = cyclohexyl, tert-butyl, ethyl), to give the corresponding iridium isocyanide complexes (PCP)Ir(CH3)(H)(CNR) (PCP = κ

NIAID Data Ecosystem70

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex

有机金属催化

反应机理

New experimental findings suggest partial revision of the currently accepted mechanism of the carbonyl hydrosilylation catalyzed by the iridium(III) pincer complex introduced by Brookhart. Employing

NIAID Data Ecosystem60

A High pressure investigation of the Manganese Carbonyls Mn(CO)5(CH3) and Mn(...

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