Rhodium Catalyzed, Carbon–Hydrogen Bond Directed Hydrodefluorination of Fluoroarenes
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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Carbon_Hydrogen_Bond_Directed_Hydrodefluorination_of_Fluoroarenes/2223577
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资源简介：
[Cp*RhCl(μ-Cl)]2 is reported as a highly efficient
and selective precatalyst for the hydrodefluorination of perfluoroarenes
using a hydrocarbon-soluble aluminum dihydride as the terminal reductant.
Reactions are directed to cleave a C–F bond adjacent to an
existing C–H bond with high regioselectivity (98.5–99%).
A heterobimetallic complex containing an extremely rare Al–H–Rh
functional group has been isolated and shown to be catalytically competent.
创建时间：
2014-12-22
