Coupled 1D Chemical Kinetic-Transport and 2D Hydrodynamic Modeling Supports a modest 1–1.5× Supersolar Oxygen Abundance in Jupiter’s Atmosphere
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http://dataverse.jpl.nasa.gov/citation?persistentId=doi:10.48577/jpl.YGZQYM
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Understanding the deep atmospheric composition of Jupiter provides critical constraints on its formation and the chemical evolution of the solar nebula. In this study, we combine one-dimensional thermochemical kinetic-transport modeling with two-dimensional hydrodynamic simulations to constrain Jupiter’s deep oxygen abundance using carbon monoxide (CO) as a proxy tracer. Leveraging a comprehensive chemical network generated by Reaction Mechanism Generator (RMG), we assess the impact of updated reaction rates, including the often-neglected but thermochemically significant Hidaka reaction (\ce{CH3OH} + H → \ce{CH3} + \ce{H2O}). Our 1D-2D coupled approach supports a modest supersolar oxygen enrichment of $1.0–1.5\times$ the solar value. We also introduce a method for deriving Jupiter's $K_{\rm zz} = 3 \times 10^6$–$5 \times 10^7$ cm$^2$/s from 2D hydrodynamic modeling using the quasi steady-state method, which is also broadly applicable to exoplanet atmospheric modeling, where $K_{\rm zz}$ remains highly uncertain but strongly influences disequilibrium chemistry and observable features. Finally, our results imply a significantly elevated planetary carbon-to-oxygen (C/O) ratio of $\sim$2.9, highlighting the importance of clarifying the mechanisms behind the preferential accretion of carbon-rich material during Jupiter's formation. By integrating thermochemical and hydrodynamic perspectives, our study offers a more complete framework for constraining chemical and dynamical processes in (exo)planetary atmospheres.
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Root
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2025-12-29



