Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2‑Alkenylphenols and Alkynes
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Rhodium_III_Catalyzed_Dearomatizing_3_2_Annulation_of_2_Alkenylphenols_and_Alkynes/2033724
下载链接
链接失效反馈官方服务：
资源简介：
Appropriately
substituted 2-alkenylphenols undergo a mild
formal [3C+2C] cycloaddition with alkynes when treated with
a Rh(III) catalyst and an oxidant. The reaction, which involves the
cleavage of the terminal C–H bond of the alkenyl moiety and
the dearomatization of the phenol ring, provides a versatile and efficient
approach to highly appealing spirocyclic skeletons and occurs
with high selectivity.
创建时间：
2015-12-17
