Intramolecular C–C Bond Coupling of Nitriles to a Diimine Ligand in Group 7 Metal Tricarbonyl Complexes
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https://figshare.com/articles/dataset/Intramolecular_C_C_Bond_Coupling_of_Nitriles_to_a_Diimine_Ligand_in_Group_7_Metal_Tricarbonyl_Complexes/2102416
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资源简介：
Dissolution of M(CO)3(Br)(LAr) [LAr = (2,6-Cl2-C6H3-NCMe)2CH2] in either acetonitrile [M = Mn, Re] or benzonitrile (M = Re) results in C–C coupling of the nitrile to the diimine ligand. When reacted with acetonitrile, the intermediate adduct [M(CO)3(NCCH3)(LAr)]Br forms and undergoes an intramolecular C–C coupling reaction between the nitrile carbon and the methylene carbon of the β-diimine ligand.
创建时间：
2016-02-12
