Data for Investigating Silicatein Selectivity and Specificity in Silicon-Oxygen Bond Condensation and Metathesis

Spreadsheets containing the numerical data in Excel and Origin format.Data including variance expressed as standard deviations.File 1. Silyl phenoxy and octyloxy condensations contain the numerical data for Table 1 and Figure S1 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethyloctyloxy silyl ether (TES-OOc), triethylphenoxy silyl ether (TES-OPh) and disiloxane (TES)2O respectively where product conversion was plotted against time.File 2. Competition reaction contains the numerical data for Figure 1 and Table S1 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethyloctyloxy silyl ether (TES-OOc) and triethylphenoxy silyl ether (TES-OPh) respectively where product conversion was plotted against time.File 3. Additives and small molecules reactions contain the numerical data for Figure 3 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethylphenoxy silyl ether (TES-OPh) and disiloxane respectively where product conversion was plotted against lyophilised additives and small molecule catalysts.File 4. Silyl transfer reactions contain the numerical data for Figure 4 and Table S3 in the paper. It contains the data for the area under the curve for the chromatographic peak corresponding to triethylphenoxy silyl ether (TES-OPh), trimethylphenoxy silyl ether (TMS-OPh) and disiloxane respectively where product conversion was plotted against time.Data including variance expressed as standard error of the mean.File 5. Silyl phenoxy and octyloxy condensations contain the numerical data for Table 1 and Figure S1 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethyloctyloxy silyl ether (TES-OOc), triethylphenoxy silyl ether (TES-OPh) and disiloxane (TES)2O respectively where product conversion was plotted against time.File 6. Competition reaction contains the numerical data for Figure 1 and Table S1 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethyloctyloxy silyl ether (TES-OOc) and triethylphenoxy silyl ether (TES-OPh) respectively where product conversion was plotted against time.File 7. Temperature profile reaction contains the numerical data for Figure 3 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethylphenoxy silyl ether (TES-OPh) and disiloxane (TES)2O respectively where product conversion was plotted against lyophilised additives and small molecule catalysts.File 8. Additives and small molecules reactions contain the numerical data for Figure 3 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethylphenoxy silyl ether (TES-OPh) and disiloxane respectively where product conversion was plotted against lyophilised additives and small molecule catalysts.File 9. Silyl transfer reactions contain the numerical data for Figure 4 and Table S3 in the paper. It contains the data for the area under the curve for the chromatographic peak corresponding to triethylphenoxy silyl ether (TES-OPh), trimethylphenoxy silyl ether (TMS-OPh) and disiloxane respectively where product conversion was plotted against time.