Gallium−Gallium Bonds as Key Building Blocks for the Formation of Large Organometallic Macrocycles, on the Way to a Mesoporous Molecule
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https://figshare.com/articles/dataset/Gallium_Gallium_Bonds_as_Key_Building_Blocks_for_the_Formation_of_Large_Organometallic_Macrocycles_on_the_Way_to_a_Mesoporous_Molecule/3354289
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资源简介：
A macrocyclic gallium carboxylate (3) is formed on reaction of the digallane(4) R2Ga−GaR2 [R = CH(SiMe3)2], 1, with naphthalene-2,6-dicarboxylic acid, HOOC−C10H6−COOH.
The macrocycle comprises 44 atoms, and four Ga−Ga single bonds are connected by four
dicarboxylato bridges. The cavity of the heterocycle may be described as a rigid molecular
square possessing a largest diameter of 1.86 nm. It encloses four 1,2-difluorobenzene
molecules.
创建时间：
2016-05-07
