Well-Defined Iron Catalyst for Improved Hydrogenation of Carbon Dioxide and Bicarbonate
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https://figshare.com/articles/dataset/Well_Defined_Iron_Catalyst_for_Improved_Hydrogenation_of_Carbon_Dioxide_and_Bicarbonate/2457334
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资源简介：
The most efficient, stable, and easy-to-synthesize non-noble
metal
catalyst system for the reduction of CO2 and bicarbonates
is presented. In the presence of the iron(II)-fluoro-tris(2-(diphenylphosphino)phenyl)phosphino]tetrafluoroborate
complex 3, the hydrogenation of bicarbonates proceeds
in good yields with high catalyst productivity and activity (TON >
7500, TOF > 750). High-pressure NMR studies of the hydrogenation
of
carbon dioxide demonstrate that the corresponding iron-hydridodihydrogen
complex 4 is crucial in the catalytic cycle.
创建时间：
2016-02-20
