N‑Heterocyclic Carbene-Catalyzed [3 + 4] Annulation of Enals and Alkenyl Thiazolones: Enantioselective Synthesis of Thiazole-Fused ε‑Lactones
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https://figshare.com/articles/dataset/N_Heterocyclic_Carbene-Catalyzed_3_4_Annulation_of_Enals_and_Alkenyl_Thiazolones_Enantioselective_Synthesis_of_Thiazole-Fused_Lactones/3384625
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资源简介：
The bifunctional
N-heterocyclic carbene catalyzed [3 + 4] annulation
of enals and 5-alkenyl thiazolones was developed, giving the corresponding
thiazole-fused ε-lactones in high yields with excellent diastereoselectivties
and enantioselectivities. The thiazole-fused ε-lactone could
be isomerized to the spirocyclic thiazolone–cyclopentanone
without erosion of enantioselectivity.
创建时间：
2016-05-27
