A Well-Defined Hydrocarbon-Soluble Calcium Hydroxide: Synthesis, Structure, and Reactivity
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https://figshare.com/articles/dataset/A_Well_Defined_Hydrocarbon_Soluble_Calcium_Hydroxide_Synthesis_Structure_and_Reactivity/3046771
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资源简介：
Controlled hydrolysis of a (β-diketiminate)calcium-amide gave a heteroleptic (β-diketiminate)calcium-hydroxide complex that is remarkably stable against ligand exchange and formation of Ca(OH)2.
The structure of this dimeric complex shows OH- units that symmetrically bridge the Ca2+ ions. This
hydrocarbon-soluble calcium hydroxide reacted rapidly with CO2 to produce a gel from which amorphous
CaCO3 slowly separated. This reaction behavior allows for sol−gel coating with CaCO3 from an organic
solvent. Reaction with benzophenone did not lead to nucleophilic attack of OH- to the carbonyl but gave
a red benzophenone adduct instead.
创建时间：
2006-11-22
