Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_Pincer-Type_Cobalt_Silyl_and_Silylene_Complexes/7189541
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资源简介:
Preparation
and characterization of a series of pincer-type [P2Si]Co
complexes are reported, including a crystal structure
of the first base-free cobalt silylene complex. The cationic silylene
complex is strongly Lewis acidic and oxophilic, readily coordinating
Lewis bases such as triflate and pyridine and heterolytically cleaving
the O–H bonds in ethanol and water.
创建时间:
2018-10-10



