Light-Triggered Catalytic Asymmetric Allylic Benzylation with Photogenerated C‑Nucleophiles
收藏Figshare2020-03-20 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Light-Triggered_Catalytic_Asymmetric_Allylic_Benzylation_with_Photogenerated_i_C_i_Nucleophiles/11926947
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Herein is reported the asymmetric allylic benzylation of Morita–Baylis–Hillman (MBH) carbonates with 2-methylbenzophenone (MBP) derivatives as nonstabilized photogenerated C-nucleophiles. The dual activation of both reaction partners, chiral Lewis-base activation of the electrophile and light activation of the nucleophile, enables the stereoselective installation of benzyl groups at the allylic position to forge tertiary and quaternary carbon centers.
创建时间：
2020-03-20
