Synthesis and Reactivity of Cationic Iridium Aminocarbenes Derived from Terminal Alkynes and 2‑Aminopyridines
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_Cationic_Iridium_Aminocarbenes_Derived_from_Terminal_Alkynes_and_2_Aminopyridines/2388676
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The reaction of a terminal alkyne (RCCH) and 2-aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ C(CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computational studies.
创建时间：
2016-02-19
