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Selective and Unusual Fluoride Ion Complexation by A Steroidal Receptor Using OH...F<sup>-</sup> and CH...F<sup>-</sup> Interactions: A New Motif for Anion Coordination?

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NIAID Data Ecosystem2026-03-06 收录
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A novel cholaphane has been synthesized from a naturally occurring bile acid in just two steps. It has an ability to bind two fluoride ions selectively utilizing the glycolate motif in chloroform. This “inside-out” cyclodextrin analogue encapsulates fluoride through O−H...F- and C−H...F- interaction.

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2016-05-06
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