Complementary Helicity Interchange of Optically Switchable Supramolecular-Enantiomeric Helicenes with (−)-Gel-Sol-(+)-Gel Transition Ternary Logic
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https://figshare.com/articles/dataset/Complementary_Helicity_Interchange_of_Optically_Switchable_Supramolecular_Enantiomeric_Helicenes_with_Gel_Sol_Gel_Transition_Ternary_Logic/2425105
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资源简介:
A gallamide-containing pseudoenantiomeric
helicene
pair bearing a (10R,11R)-dimethoxymethyldibenzosuberane
core can self-assemble by intermolecular amide H-bonding and π-π
stacking into bundled helical fibers with helical tunnels of complementary
helicity in CH2Cl2. The helicenes undergo excellent
complementary photoswitchings of ternary logic at 280, 318, and 343
nm through (−)-gel-sol-(+)-gel interconversion.
创建时间:
2016-02-19



