A New Catalytic Mechanism of Periplasmic Nitrate Reductase from Desulfovibrio desulfuricans ATCC 27774 from Crystallographic and EPR Data and based on detailed analysis of the sixth ligand

A New Catalytic Mechanism of Periplasmic Nitrate Reductase from Desulfovibrio desulfuricans ATCC 27774 from Crystallographic and EPR Data and based on detailed analysis of the sixth ligand Descriptor: 2-AMINO-5,6-DIMERCAPTO-7-METHYL-3,7,8A,9-TETRAHYDRO-8-OXA-1,3,9,10-TETRAAZA-ANTHRACEN-4-ONE GUANOSINE DINUCLEOTIDE, IRON/SULFUR CLUSTER, MOLYBDENUM ATOM, ... Authors: Najmudin, S, Gonzalez, P.J, Trincao, J, Coelho, C, Mukhopadhyay, A, Romao, C.C, Moura, I, Moura, J.J.G, Brondino, C.D, Romao, M.J. Deposit date: 2007-06-28 Release date: 2008-03-18 Last modified: 2023-12-13 Method: X-RAY DIFFRACTION (2.44 Å) Cite: Periplasmic Nitrate Reductase Revisited: A Sulfur Atom Completes the Sixth Coordination of the Catalytic Molybdenum. J.Biol.Inorg.Chem., 13, 2008

基于晶体学数据与电子顺磁共振（EPR）数据，并通过对第六配体的详尽分析，阐明脱硫弧菌（Desulfovibrio desulfuricans）美国典型培养物保藏中心（American Type Culture Collection, ATCC）27774菌株周质硝酸还原酶（Periplasmic Nitrate Reductase）的新型催化机制。配体描述信息：2-氨基-5,6-二巯基-7-甲基-3,7,8A,9-四氢-8-氧杂-1,3,9,10-四氮杂蒽-4-酮、鸟苷二核苷酸、铁硫簇、钼原子……作者：Najmudin, S.、Gonzalez, P.J.、Trincao, J.、Coelho, C.、Mukhopadhyay, A.、Romao, C.C.、Moura, I.、Moura, J.J.G.、Brondino, C.D.、Romao, M.J.提交日期：2007年6月28日；发布日期：2008年3月18日；最后修改日期：2023年12月13日；研究方法：X射线衍射（分辨率2.44 Å）；引用文献：《周质硝酸还原酶的重新审视：一个硫原子完成催化钼的第六配位》，《生物无机化学期刊》（J. Biol. Inorg. Chem.），第13卷，2008年。