Diarylrhodates as Promising Active Catalysts for the Arylation of Vinyl Ethers with Grignard Reagents
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https://figshare.com/articles/dataset/Diarylrhodates_as_Promising_Active_Catalysts_for_the_Arylation_of_Vinyl_Ethers_with_Grignard_Reagents/2278663
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资源简介：
Anionic diarylrhodium complexes,
generated by reacting [RhCl(cod)]2 with 2 equiv of aryl
Grignard reagents, were found to be
effective active catalysts in cross-coupling reactions of vinyl ethers
with aryl Grignard reagents, giving rise to the production of vinyl
arenes. In this catalytic system, vinyl-O bonds were preferably cleaved
over Ar–O or Ar–Br bonds. A lithium rhodate complex
was isolated, and its crystal structure was determined by X-ray crystallography.
创建时间：
2014-07-02
