An Infinite Zigzag Chain of Alternating Cl−Pd−Pd−Cl and Mo−Mo Units
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https://figshare.com/articles/dataset/An_Infinite_Zigzag_Chain_of_Alternating_Cl_Pd_Pd_Cl_and_Mo_Mo_Units/3320245
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资源简介：
Treatment of Pd2Cl2(CNC6H3Me2-2,6)4 (1) with Mo2(O2CCF3)4 (2) in dichloromethane afforded an infinite zigzag
chain {[Pd2Cl2(CNC6H3Me2-2,6)4][Mo2(O2CCF3)4]}n (3), where two metal−metal bonded dinuclear Pd−Pd and Mo−Mo units were bridged by chloro atoms. The Mo−Mo distance (2.1312(3) Å) of 3 is significantly elongated compared
to that of 2 (2.090(4) Å) and lies in the range of that of the quadruple Mo−Mo bonded complexes. Such elongation
might be attributed to the axial donation of the chloro atoms of the Pd−Pd unit to the Mo−Mo moiety.
创建时间：
2004-10-18
