Ruthenium-Mediated Double C–H Activation of Toluene with 1‑Azidoadamantane
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https://figshare.com/articles/dataset/Ruthenium_Mediated_Double_C_H_Activation_of_Toluene_with_1_Azidoadamantane/2480158
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资源简介：
Reaction of [LOEtRuCl2]2 (LOEt– = [CpCo{P(O)(OEt)2}3]−) (1) with the organic
azides RN3 in CH2Cl2 at room temperature,
followed by recrystallization from Et2O, afforded [LOEtRuCl2(NH2R)] (R = Ph (2), 4-NO2C6H4 (3), 1-adamantyl
(Ad) (4)). Complex 1 can catalyze the reduction
of 4-nitrophenyl azide to 4-nitroaniline by cyclohexene. Heating 1 with AdN3 in toluene at reflux led to formation
of the cyclometalated Ru(III) complex [LOEtRu(κ2C,N-AdNCHC6H4)Cl] (5), possibly via double C–H
activation of toluene by an imido intermediate. The crystal structures
of 3 and 5 have been determined.
创建时间：
2016-02-20
