Stereoselective Synthesis of the Eastern Quinolizidine Portion of Himeradine A
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https://figshare.com/articles/dataset/Stereoselective_Synthesis_of_the_Eastern_Quinolizidine_Portion_of_Himeradine_A/2626092
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资源简介：
The synthesis of the C15–C17/N1′–C11′ quinolizidine portion of himeradine A is disclosed. An intramolecular, heteroatom Michael addition was employed to establish the C6′ stereogenic center with high diastereoselectivity. The quinolizidine ring was constructed using microwave-induced cyclization at the N1′–C2′ position. The C17 stereogenic center was introduced through a diastereoselective Overman rearrangement.
创建时间：
2016-02-23
