Conversion of Carbon Dioxide to Oxalate by α‑Ketocarboxylatocopper(II) Complexes
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https://figshare.com/articles/dataset/Conversion_of_Carbon_Dioxide_to_Oxalate_by_Ketocarboxylatocopper_II_Complexes/2263249
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资源简介：
The
α-ketocarboxylatocopper(II) complex [{Cu(L1)}{O2CC(O)CH(CH3)2}] can be spontaneously converted into the binuclear
oxalatocopper(II) complex [{Cu(L1)}2(μ-C2O4)] upon exposure to O2/CO2 gas. 13C-labeling experiments revealed that oxalate ions partially
incorporated 13CO2 molecules. Furthermore, the
bicarbonatocopper(I) complex (NEt4)[Cu(L1){O2C(OH)}] in an Ar atmosphere and the α-ketocarboxylatocopper(I)
complex Na[Cu(L1){O2CC(O)CH(CH3)2}] in an O2 atmosphere were also transformed spontaneously
into the oxalato complex [{Cu(L1)}2(μ-C2O4)].
创建时间：
2016-02-17
