Alkynyl Complexes of High-Valence Clusters. Synthesis and Luminescence Properties of [Mo6I8(CCC(O)OMe)6]2–, the First Complex with Exclusively Organometallic Outer Ligands in the Family of Octahedral {M6X8} Clusters
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https://figshare.com/articles/dataset/Alkynyl_Complexes_of_High_Valence_Clusters_Synthesis_and_Luminescence_Properties_of_Mo_sub_6_sub_I_sub_8_sub_C_CC_O_OMe_sub_6_sub_sup_2_sup_the_First_Complex_with_Exclusively_Organometallic_Outer_Ligands_in_the_Family_of_Octahedral_M_sub_6_sub_X_sub_8_sub/2558356
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资源简介：
The reaction of [Mo6I14]2– with methyl propiolate HCCC(O)OMe in the presence of Ag+ and Et3N yielded the new luminescent complex [Mo6I8(CCC(O)OMe)6]2–, the first fully organometallic complex in the family of octahedral {M6X8} clusters. The cluster was crystallized as tetraphenylphosphonium salt and characterized by X-ray single-crystal diffraction and elemental analyses, mass spectrometry, 13C NMR, UV–vis, and luminescence spectroscopies.
创建时间：
2016-02-22
