Organo-Zintl Clusters Soluble in Conventional Organic Solvents: Setting the Stage for Organo-Zintl Cluster Chemistry
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下载链接：
https://figshare.com/articles/dataset/Organo_Zintl_Clusters_Soluble_in_Conventional_Organic_Solvents_Setting_the_Stage_for_Organo_Zintl_Cluster_Chemistry/2967217
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资源简介：
Organo-Zintl cluster ions were synthesized by reactions of alkynes
with Ge94- clusters in ethylenediamine. The triple bonds are hydrogenated to double bonds during the process. The resulting dial-kenylated species [RHCCHGe9CHCHR]2- have lower charge,
their alkali-metal cations can be exchanged for tetralkylammonium
cations, and the resulting compounds are soluble in nonpolar
solvents. This was demostrated with [H2CCHGe9CHCH2]2-,
which was structurally characterized with [K-(18-crown-6)]+, [Me4N]+,
and [Pr4N]+ as countercations. The solubility of its salt with [Oc4N]+
in various conventional organic solvents was studied.
创建时间：
2016-06-03
