Sequential Reduction and Alkyl Exchange Reactions of Bis(imino)pyridine Dialkyliron(II) with Trimethylaluminum
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https://figshare.com/articles/dataset/Sequential_Reduction_and_Alkyl_Exchange_Reactions_of_Bis_imino_pyridine_Dialkyliron_II_with_Trimethylaluminum/2306440
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资源简介：
The
sequence of reactions ensuing when the 2,6-bis(imino)pyridine
Fe(II) dialkyl complexes [Fe(CH2SiMe3)2(BIP)] react with trimethylaluminum is described in detail. The first
step is the reduction of the dialkyl to the corresponding monoalkyl
complex [Fe(CH2SiMe3)(BIP)]. In the presence
of an excess of trimethylaluminum, these undergo exchange of the remaining
CH2SiMe3 group for methyl, and ultimately the
methyliron fragment is displaced from the complex, leading to previously
known paramagnetic aluminum compounds. The diethylaluminum complex
[AlEt2(iPrBIP)] was obtained when triethylaluminum was used instead
of trimethylaluminum.
创建时间：
2016-02-17
