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Polymer Building Blocks: Self-Assembly of Silver(I) Cyclotriphosphazene Cationic Columns

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Polymer_Building_Blocks_Self_Assembly_of_Silver_I_Cyclotriphosphazene_Cationic_Columns/3262765
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The multimodal ligand hexakis(2-pyridyloxy)cyclotriphosphazene (L) and its 4-methyl-2-pyridyloxy analogue (MeL) react with Ag(I) to afford {[AgL]+}∞ supramolecular cationic columns via self-assembly, with the anions occupying the intercolumnar channels. In contrast, the reaction of MeL with Cu(I) yields a dimetallic Cu(II) complex containing μ-OH and μ-4-methyl-2-pyridyloxylato bridges.
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2005-10-17
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